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Creators/Authors contains: "Petronotis, Katerina E."

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  1. Abstract

    Authigenic greigite may form at any time within a sediment during diagenesis. Its formation pathway, timing of formation, and geological preservation potential are key to resolving the fidelity of (paleo‐)magnetic signals in greigite‐bearing sediments. In the cored sequence of the International Ocean Discovery Program Expedition 362 (Sumatra Subduction Margin), multiple organic‐rich mudstone horizons have high magnetic susceptibilities. The high‐susceptibility horizons occur immediately below the most bioturbated intervals at the top of muddy turbidite beds. Combined mineral magnetic, microscopic, and chemical analyses on both thin sections and magnetic mineral extracts of sediments from a typical interval (∼1,103.80–1,108.80 m below seafloor) reveal the presence of coarse‐grained greigite aggregates (particles up to 50–75 μm in size). The greigite formed under nonsteady state conditions caused by the successive turbidites. Organic matter, iron (oxy)(hydr)oxides, Fe2+, and sulfides and/or sulfate were enriched in these intensively bioturbated horizons. This facilitated greigite formation and preservation within a closed diagenetic system created by the ensuing turbidite pulse, where pyritization was arrested due to insufficient sulfate supply relative to Fe (oxy)(hydr)oxide. This may represent a novel greigite formation pathway under conditions modulated by turbidites and bioturbation. Paleomagnetic analyses indicate that the early diagenetic greigite preserves primary (quasi‐)syn‐sedimentary magnetic records. The extremely high greigite content (0.06–1.30 wt% with an average of 0.50 wt% estimated from their saturation magnetization) implies that the bioturbated turbiditic deposits are an important sink for iron and sulfur. Mineral magnetic methods, thus, may offer a window to better understand the marine Fe–S–C cycle.

     
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  2. Abstract

    The Pāpaku Fault Zone, drilled at International Ocean Discovery Program (IODP) Site U1518, is an active splay fault in the frontal accretionary wedge of the Hikurangi Margin. In logging‐while‐drilling data, the 33‐m‐thick fault zone exhibits mixed modes of deformation associated with a trend of downward decreasing density,P‐wave velocity, and resistivity. Methane hydrate is observed from ~30 to 585 m below seafloor (mbsf), including within and surrounding the fault zone. Hydrate accumulations are vertically discontinuous and occur throughout the entire logged section at low to moderate saturation in silty and sandy centimeter‐thick layers. We argue that the hydrate distribution implies that the methane is not sourced from fluid flow along the fault but instead by local diffusion. This, combined with geophysical observations and geochemical measurements from Site U1518, suggests that the fault is not a focused migration pathway for deeply sourced fluids and that the near‐seafloor Pāpaku Fault Zone has little to no active fluid flow.

     
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